Control of environmental pollution in tall oil fractionation

ABSTRACT

Tall oil is fractionated with little or no environmental pollution. The stripping steam and the odorous compounds it carries with it are condensed by foul water being recycled through the condenser, an amount of foul water equal to the stripping steam coming into the condenser being purged, revaporized and used again as stripping steam in the fractionation process.

United States Patent [191 Bress 11 E Re. 28,476

[ Reissued July 8, 1975 CONTROL OF ENVIRONMENTAL POLLUTION IN TALL OILFRACTIONATION [75] Inventor: Dellason F. Bress, Murray Hill, NJ.

[73] Assignee: Foster Wheeler Energy Corporation,

Livingston, NJ.

[22] Filed: Aug. 8, 1973 [21] Appl. No.: 391,892

Related U.S. Patent Documents [51] Int. Cl. C09f 1/00 [58] Field ofSearch 260/97.6; 203/4, 87, 97; 202/182, 202

Primary Examiner-Melvyn l. Marquis Assistant ExaminerWilliam ParkerAttorney, Agent, or FirmJohn E. Wilson; Marvin A. Naigur [5 7 ABSTRACTTall oil is fractionated with little or no environmental pollution. Thestripping steam and the odorous compounds it carries with it arecondensed by foul water being recycled through the condenser, an amountof foul water equal to the stripping steam coming into the condenserbeing purged, revaporized and used again as stripping steam in thefractionation process.

14 Claims, 1 Drawing Figure Reissued July 8, 1975 INVENTOR. DELLASON FBRESS ATTORNEY CONTROL OF ENVIRONMENTALPOLLUTION IN TALL OILFRACTIONATION Matter enclosed in heavy brackets appears in the originalpatent but forms no part of this reissuespecification; matter printed initalics indicates the additions made by reissue.

BACKGROUND OF THE INVENTION The fractionation of tall oil isconventionally carried out under vacuum using stripping steam whichcarries from the top of the fractionation column the most volatile andtherefore the most odorous of the unsaponifable material in the crude. Acondenser communicates with the top of the column to maintain the vacuumand transform most of the stripping steam and low boiling odorouscompounds into liquid.

In one type of system being used presently, the condenser is of thebarometric type and the cooling water is recirculated foul water fromthat condenser. After the condenser, the water is usually passed througha settling pond to remove an oil layer after which the water iscirculated over a cooling tower and returned to the condenser. The useof a settling pond is advisable since it minimizes gunking of thecooling tower.

A disadvantage to such a system is that it creates an air pollutionproblem since the cooling tower air strips odors from the oily water.This is true whether or not a settling pond is used. The odor producedis not wholly unpleasant but is extremely strong particularly whenredistilling the heads produced to make the prime products. Whileobjectionable, the odor is not considered hazardous and presents nohealth problem. This type of system reduces to a minimum any problemsassociated with stream pollution because under most weather conditionsthe evaporative loss from the cooling towerexceeds the stripping steamadded to the system in the barometric condenser. Thus there is no foulwaste water except in extended periods of rainy weather.

A two-stage jet with intercondenser usually follows the first condenser.The first condenser removes essentially all the organic contaminants sothat a relatively pure stream of non-condensable gases and water enterthe two-stage system and the condensate produced by the two-stage systemis therefore not objectionable.

Another type of system which is used at the present time is one wherevacuum surface condensers are used for the stripping steam. This isslightly more expensive than the barometric type even though the latterrequires a separate clean water cooling tower. The surface condenserdoes eliminate the odor from the cooling tower but a foul stream ofcondensate equivalent to the stripping steam is produced.

Still another system in present use employs a closed barometriccondensing system with a cooler to cool the circulating foul waterindirectly with air or water. A purge from the water circulating,equivalent to the stripping steam, is then produced as a polluted streamwhich requires further treatment.

It can be seen that the tall oil distillation plants in present usecreate both air and stream pollution problems. Recently the trend hasbeen toward the closed condensing systems. The stream of polluted waterresulting from such systems is often-treated, but complete purificationhas been too difficult and expensive to be practicable. Mechanical andchemical treatment systems have been used, but only with limitedsuccess. In addition, biological treatments in conventional aeratedactivated sludge plants have been performed on tall oil wastes.

The polluted water stream even after settling will contain as much asone percent (1%) of dissolved and emulsified organic chemicals/These aremainly unsaponifiable materials as contrasted to the rosin and fattyacid which make up the bulk of the crude tall oil in the distillationsystem. These include sterols, hydrocarbons, terpenes, alcohols as wellas decomposition products resulting from the cracking of fatty acidrosin in the distillation process.

SUMMARY It is an object of this invention to overcome disadvantagesfound in the prior art as those discussed above. The polluted stream ofwaste liquid resulting from the condensation of the stripping stream iseliminated. This is accomplished by treating and recycling the waterpurge and revaporizing it to once again utilize it as stripping steam inthe distillation process.

BRIEF DESCRIPTION OF THE DRAWING The drawing is a schematic view of thepresent invention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT In the drawing a stream1 of stripping steam plus contaminants from a fractionation tower (notshown) leads to a condenser 2 which may be of the barometric type. Foulwater from the condenser 2 flows through line 3 to a hot well 4 fromwhich a pump 5 circulates it by line 6 to a cooler 7. The cooler 7 isfed coolant through a line 8 which cools the foul water which is thenreturned to the condenser 2 through line 9.

Noncondensable gases from theflhot well 4 are vented by line 4a.Preferably, the gases are not vented directly to the atmosphere but aredisposed of by incineration, an elevated stack or by other means whichwould eliminate any odor.

Noncondensible gases coming out of the condenser 2 through line 10 havewater vapor with little if any organic content. The noncondensible gasesflowing through line 10 are compressed in a multi-staging steamevaporator system 11 having an interstaging condenser 12 from which thecondensates lead to a hot well 13 from which it overflows to a sewer orother water system through line 14. It has already been pointed out thatthe condensate from the interstaging condenser is not objectionable.Gases from the hot well 13 are disposed of in the same manner as thegases vented through line 4a.

A portion of the circulating water coming out of the pump 5 is purged byline 16. The amount of water which is purged is such that in any giventime, it will be approximately equal to the amount of stripping steamcondensed in the condenser 2. The water in the line 16 is heated in theheat exchanger 17 which is fed heating medium through a line 18. Theheating medium may be steam, flue gas or a hot process stream. Suchheating promotes the separation of emulsified organic material when thewater is led to a coalescing filter 19 through line 20.

The liquid then flows through line 21 to a decanter 22 which is suitablybaffled to separate the organic or oil phase from the water phase. Theorganic phase leaves through line 23 and may then be added to lowgradefractions produced in the tall oil plant or it may be burned. Gases arevented through line 24 any may be treated in the same manner as thegases which are vented through lines 4a and 15.

The water phase passes through line 25 to a stripper vessel 26 in whicha small amount of steam is injected through line 27 to strip odors fromthe water. The vapor from the stripper 26 passes through line 28 and ispreferably treated in the same manner as the gases vented through lines4a, 15 and 24. Stripped water from the stripper 26 passes through a line29 to a surge tank 30 having a floating suction drain 31 which is usedto remove any remaining organic which is separating from the waterphase. The organic material exiting through line 31 is added to thematerial leaving through line 23 to be treated in the same manner as thematerial flowing in that line. Gases leave surge tank 30 through line30a and are treated as the gases flowing out through lines 4a, 15, 24and 28.

After passing through the surge tank 30, the water passes through line32 to a pump 33 which forces it through line 34 to an activated carbontreating vessel 35 which enhances the quality of the water. Afterpassing through the vessel 35, the water is led through a line 36 to avaporizer 37 which employs a heating coil 38 to vaporize the water. Theheating coil 38 uses a heating medium such as hot process stream or lowpressure steam. Organic material which is separated from the water inthe vaporizer 37 is withdrawn through line 39 and added to thatwithdrawn through lines 23 and 31. The. vaporized water passes throughline 40 to be used as stripping steam in the fractionation process.

It should be appreciated that the present invention eliminates air andwater pollution. it should also be appreciated that it obviates thetreatment of boiler feed water, In conventional systems, the strippingsteam is generated in a boiler and then used in the fractionating tower.Subsequently, it is condensed and the condensates are purged. Byutilizing boiler steam, hot process fluid or other. means to revaporize,the condensate for reuse, the need for fresh boiler feed water iseliminated.

What is claimed is:

1. A plant for treating the stripping steam and odorous material carriedtherein after stripping a tall oil fractionating tower in a manner toreduce pollution comprising:

a conduit circuit, said circuit comprising:

a condenser for condensing said steam, said condenser having an inletand outlet, the outlet and inlet of said condenser being connected witheach other by said circuit so that condensate from said condenser isrecirculated from the outlet thereof through the inlet thereof;

a purging outlet to purge from said circuit a portion of the circulatingwater and entrained odorous material at a rate of flow approximatelyequal to the rate at which said stripping steam enters said condenser;

a vaporizer connected with said purging outlet for vaporizing thecondensate and entrained odorous matter coming through said outlet, toseparate it from the entrained organic material;

a conduit connected between said vaporizer and said fractionating towerfor directing the vapor from said vaporizer to said fractionating tower;and

means between said purging outlet and said vaporizer to separate fromsaid odorous material and water, non-condensible gases, so that saidnoncondensible gases can be incinerated.

2. The plant defined in claim 1 further comprising means to separate theoil and the water phases of said mixture and remove said oil phasebefore said water phase is fed to said vaporizer.

3. The plant defined in claim 1 further comprising means to removeorganic material from said water before said water is fed to saidvaporizer.

4. The plant defined in claim 3 further comprising a surge tankconnected between said means to remove organic material and saidvaporizer.

5. A method of treating the mixture of stripping steam and odorousmaterial carried therein after said steam has been used to strip talloil being fractionated comprising the steps of:

condensing said steam continuously by heat exchange of said mixture withwater,

recirculating the resulting mixture to reuse it to condense said steam,

purging a portion of said resulting mixture at a rate of flowapproximately equal to the rate at which said steam is condensed,

separating non-condensible gases from said purged portion of saidresulting mixture and incinerating said non-condensible gases,

vaporizing a part of said purged portion, and

using the vaporized part of said purged portion as said stripping steam.

6. The method defined in claim 5 comprising the further step of removingorganic material from said purged portion before vaporizing it.

7. The method defined in claim 6 comprising the further step ofseparating the water and oil phases of said resulting mixture andremoving said oil phase before vaporizing said water phase.

8. A plant for treating the stripping steam and odorous material carriedtherein after stripping a tall oil fractionating tower in a manner toreduce pollution comprising:

a condenser connected with said fractionating tower for condensing saidsteam;

a line connected with said condenser for flowing out of said condensercondensate and entrained odorous material;

a vaporizer connected with said line for vaporizing the condensate andentrained odorous material coming through said line to separate it fromthe entrained organic material;

a conduit connected between said vaporizer and said fractionating towerfor directing the vapor from said vaporizer to said fractionating tower;and

means between said line and said vaporizer to separate from said odorousmaterial and water, noncondensible gases, so that said non-condensiblegases can be incinerated.

9. The plant defined in claim 8 further comprising means to separate theoil and water phases of said mixtures and remove said oil phase beforesaid water phase is fed to said vaporizer.

10. The plant defined in claim 8 further comprising means to removeorganicmaterialfrom said water before said water is fed to saidvaporizer.

vaporizing said condensate; and

using the vaporized condensate as said stripping steam.

13. The method defined in claim 12 comprising the further step ofremoving organic material from said purged portion before vaporizing it.

14. The method defined in claim 13 comprising the further step ofseparating the water and oil phases of said resulting mixture andremoving said oil phase before vaporizing said water phase.

1. A PLANT FOR TREATING THE STRIPPING STEAM AND ODOROUS MATERIAL CARRIEDTHEREIN AFTER STRIPPING A TALL OIL FRACTIONATING TOWER IN A MANNER TOREDUCE POLLUTION COMPRISING: A CONDUIT CIRCUIT, SAID CIRCUIT COMPRISING:A CONDENSER FOR CONDENSING SAID STEAM, SAID CONDENSER HAVING AN INLETAND OUTLET, THE OUTLET AND INLET OF SAID CONDENSER BEING CONNECTED WITHEACH OTHER BY SAID CIRCUIT SO THAT CONDENSATE FROM SAID CONDENSER ISRECIRCULATED FROM THE OUTLET THEREOF THROUGH THE INLET THEREOF, APURGING OUTLET TO PURGE FROM SAID CIRCUIT A PORTION OF THE CIRCULATINGWATER AND ENTRAINED ODOROUS MATERIAL AT A RATE OF FLOW APPROXIMATELYEQUAL TO THE RATE AT WHICH SAID STRIPPING STEAM ENTERS SAID CONDENSER, AVAPORIZER CONNECTED WITH SAID PURGING OUTLET FOR VAPORIZING THECONDENSATE AND ENTRAINED ODOROUS MATTER COMING THROUGH SAID OUTLET, TOSEPARATE IT FROM THE ENTRAINED ORGANIC MATERIAL, A CONDUIT CONNECTEDBETWEEN SAID VAPORIZER AND SAID FRACTIONATING TOWER FOR DIRECTING THEVAPOR FROM SAID VAPORIZER TO SAID FRACTIONATING TOWER, AND MEANS BETWEENSAID PURGING OUTLET AND SAID VAPORIZER TO SEPARATE FROM SAID ODOROUSMATERIAL AND WATER, NON-CONDENSIBLE GASES, SO THAT SAID NON-CONDENSIBLEGASES CAN BE INCINERATED.
 2. The plant defined in claim 1 furthercomprising means to separate the oil and the water phases of saidmixture and remove said oil phase before said water phase is fed to saidvaporizer.
 3. The plant defined in claim 1 further comprising means toremove organic material from said water before said water is fed to saidvaporizer.
 4. The plant defined in claim 3 further comprising a surgetank connected between said means to remove organic material and saidvaporizer.
 5. A method of treating the mixture of stripping steam andodorous material carried therein after said steam has been used to striptall oil being fractionated comprising the steps of: condensing saidsteam continuously by heat exchange of said mixture with water,recirculating the resulting mixture to reuse it to condense said steam,purging a portion of said resulting mixture at a rate of flowapproximately equal to the rate at which said steam is condensed,separating non-condensible gases from said purged portion of saidresulting mixture and incinerating said non-condensible gases,vaporizing a part of said purged portion, and using the vaporized partof said purged portion as said stripping steam.
 6. The method defined inclaim 5 comprising the further step of removing organic material fromsaid purged portion before vaporizing it.
 7. The method defined in claim6 coMprising the further step of separating the water and oil phases ofsaid resulting mixture and removing said oil phase before vaporizingsaid water phase.
 8. A plant for treating the stripping steam andodorous material carried therein after stripping a tall oilfractionating tower in a manner to reduce pollution comprising: acondenser connected with said fractionating tower for condensing saidsteam; a line connected with said condenser for flowing out of saidcondenser condensate and entrained odorous material; a vaporizerconnected with said line for vaporizing the condensate and entrainedodorous material coming through said line to separate it from theentrained organic material; a conduit connected between said vaporizerand said fractionating tower for directing the vapor from said vaporizerto said fractionating tower; and means between said line and saidvaporizer to separate from said odorous material and water,non-condensible gases, so that said non-condensible gases can beincinerated.
 9. The plant defined in claim 8 further comprising means toseparate the oil and water phases of said mixtures and remove said oilphase before said water phase is fed to said vaporizer.
 10. The plantdefined in claim 8 further comprising means to remove organic materialfrom said water before said water is fed to said vaporizer.
 11. Theplant defined in claim 10 further comprising a surge tank connectedbetween said means to remove organic material and said vaporizer.
 12. Amethod of treating the mixture of stripping steam and odorous materialcarried therein after said steam has been used to strip tall oil beingfractionated comprising the steps of: condensing said steam continuouslyby heat exchange of said mixture with water; removing the condensate andthe entrained non-condensible gases from said condenser; vaporizing saidcondensate; and using the vaporized condensate as said stripping steam.13. The method defined in claim 12 comprising the further step ofremoving organic material from said purged portion before vaporizing it.14. The method defined in claim 13 comprising the further step ofseparating the water and oil phases of said resulting mixture andremoving said oil phase before vaporizing said water phase.